Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries.
نویسندگان
چکیده
A polymer gel electrolyte using AlCl3 complexed acrylamide as a functional monomer and acidic ionic liquid based on a mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 (EMImCl-AlCl3, 1-1.5, in molar ratio) as a plasticizer has been successfully prepared for the first time via free radical polymerization. Aluminum deposition is successfully achieved using a polymer gel electrolyte containing 80 wt% ionic liquid. The polymer gel electrolytes are also good candidates for rechargeable aluminum ion batteries.
منابع مشابه
Electrochemical properties of an aluminum anode in an ionic liquid electrolyte for rechargeable aluminum-ion batteries.
An aluminum metal, both native and with a very thin oxide film, was investigated as an anode for aluminum-ion batteries. Investigations were carried out in an acidic ionic liquid electrolyte, composed of AlCl3 in 1-ethyl-3-methylimidazolium chloride ([EMIm]Cl), with β-MnO2/C as a cathode. The battery based on Al metal with a very thin oxide film showed high capacity and stable surface corrosion.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 2 شماره
صفحات -
تاریخ انتشار 2016